Align the column headers as a center using apex:dataTable
Yes this is possible, you have to create a css class in your VF page. And then include in apex:column
Like this,

<apex:page standardController="Account" extensions="AccountContacts">
<apex:form id="frm">
<apex:pageBlock title="Accounts Info">
<apex:pageBlockTable value="{!lstacc}" var="lacc">
<apex:column headerValue="Name" headerClass="clsCenter">
<apex:commandLink value="{!}" onclick="show('{!}'); return false;"/>
<apex:column value="{!lacc.type}"/>

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I am Sakthivel Madesh, a certified Salesforce Advanced Developer & Administrator working on Salesforce Technology since 2011. I am currently working in Techforce Services as Sr. Salesforce Developer. I have worked on multiple technologies Like PHP, Java, Salesforce, I am very passionate about Salesforce and to earn 15x Salesforce Certification. I love Trailhead for learning Salesforce Skill and Become a Trailhead 5x Ranger too. I Love to Learn & Share my Salesforce knowledge to Salesforce Learners/Beginner using My Blog and Salesforce Community.

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